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CO(2) Recovery: Improved Performance with a Newly Developed System

Peer-Reviewed Paper

MBAA TQ vol. 45, no. 2, 2008, pp. 84-89  |  VIEW ARTICLE

Ulrich Buchhauser (1), Jadran Vrabec (2), Martin Faulstich (1), and Roland Meyer-Pittroff (3). 1. Institute of Resource and Energy Technology, TU M�nchen, Freising, Germany. 2. Institute of Thermodynamics and Thermal Process Engineering, University of Stuttgart, Stuttgart, Germany. 3. CPW Competence Pool Weihenstephan, TU M�nchen, Freising, Germany.

Abstract
State-of-the-art CO(2) recovery systems gain up to 2�2.5 kg of CO(2) per hL of cooled wort (CW) out of approx. 4.2 kg of CO(2) per hL of CW released during fermentation. The system presented in this paper enables breweries to recover up to 3.5 kg of CO(2) per hL of CW. To increase the amount of collected CO(2), it was necessary to begin recovery earlier than the usual 24 h after the start of fermentation. As a result, the input purity of CO(2) decreased from 99.5 to 95%. Based on a theoretical approach using equation of state (EOS) of the ternary mixture CO(2)+O(2)+N(2), a recovery system was developed with a 223 K fluidizing temperature of the fermentation CO(2) to separate the additional amount of O(2). To reach this cooling temperature, a second cooling stage with CO(2) as the cooling agent was added to the existing cooling device of the brewery. The installed device reached an output purity of CO(2) of 99.998%, with an O(2) concentration of 5 mg/kg.

Keywords: carbon dioxide, CO(2), CO(2) recovery, equation of state, two-stage cooling device

 

S�ntesis
Sistemas de recuperaci�n de CO(2) de vanguardia pueden recuperar hasta 2�2.5 kg de CO(2) por hL de mosto fr�o (MF), de los aprox. 4.2 kg formados durante la fermentaci�n. El sistema presentado aqu� permite que se recupere hasta 3.5 kg de CO(2) por hL de MF. Para aumentar la cantidad de CO(2) recuperada, fue necesario iniciar la recuperaci�n antes de las 24 h despu�s del inicio de la fermentaci�n, por lo que la pureza del CO(2) disminuy� de 99.5 a 95%. Se desarroll� un sistema de recuperaci�n, utilizando ecuaciones de estado f�sico teor�ticos para la mezcla terciaria de CO(2)+O(2)+N(2), con una temperatura de 223 K de fluidizaci�n del CO(2) para as� separar el exceso de O(2). Para alcanzar esta temperatura, se le agreg� al enfriador existente una segunda etapa de enfriamiento utilizando CO(2) como medio de enfriamiento. La instalaci�n alcanz� una pureza final de 99.998% con una concentraci�n de O(2) de 5 mg/kg.

Palabras claves: CO(2), dispositivo para enfriamiento en dos etapas, ecuaci�n de estado f�sico, gas carb�nico, recuperaci�n de CO(2)

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